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Uedu Open / Physical Chemistry
5.61

Physical Chemistry

Prof. Robert Field | Fall 2017
Science & Math Chemistry Physical Chemistry Science
前往原始課程
CC BY-NC-SA 4.0
課程簡介
This course is an introduction to quantum mechanics for use by chemists. Topics include particles and waves, wave mechanics, semi-classical quantum mechanics, matrix mechanics, perturbation theory, molecular orbital theory, molecular structure, molecular spectroscopy, and photochemistry. Emphasis is on creating and building confidence in the use of intuitive pictures.
課程資訊
來源MIT 開放式課程
科系Chemistry
語言English
影片數36
課程影片 (36)
1
1. Quantum Mechanics—Historical Background, Photoelectric Effect, Compton Scattering
1. Quantum Mechanics—Historical Background, Photoelectric Effect, Compton Scattering
2
2. Wave Nature of the Electron and the Internal Structure of an Atom
2. Wave Nature of the Electron and the Internal Structure of an Atom
3
3. Two-Slit Experiment; Quantum Weirdness
3. Two-Slit Experiment; Quantum Weirdness
4
4. Classical Wave Equation and Separation of Variables
4. Classical Wave Equation and Separation of Variables
5
5. Quantum Mechanics: Free Particle and Particle in 1D Box
5. Quantum Mechanics: Free Particle and Particle in 1D Box
6
6. 3-D Box and QM Separation of Variables
6. 3-D Box and QM Separation of Variables
7
7. Classical Mechanical Harmonic Oscillator
7. Classical Mechanical Harmonic Oscillator
8
8. Quantum Mechanical Harmonic Oscillator
8. Quantum Mechanical Harmonic Oscillator
9
9. The Harmonic Oscillator: Creation and Annihilation Operators
9. The Harmonic Oscillator: Creation and Annihilation Operators
10
10. The Time-Dependent Schrödinger Equation
10. The Time-Dependent Schrödinger Equation
11
11. Wavepacket Dynamics for Harmonic Oscillator and PIB
11. Wavepacket Dynamics for Harmonic Oscillator and PIB
12
12. Catch Up and Review & Postulates
12. Catch Up and Review & Postulates
13
13. From Hij Integrals to H Matrices I
13. From Hij Integrals to H Matrices I
14
14. From Hij Integrals to H Matrices II
14. From Hij Integrals to H Matrices II
15
15. Non-Degenerate Perturbation Theory I
15. Non-Degenerate Perturbation Theory I
16
16. Non-Degenerate Perturbation Theory II: HO using a,a†
16. Non-Degenerate Perturbation Theory II: HO using a,a†
17
17. Rigid Rotor I; Orbital Angular Momentum
17. Rigid Rotor I; Orbital Angular Momentum
18
18. Rigid Rotor II. Derivation by Commutation Rules
18. Rigid Rotor II. Derivation by Commutation Rules
19
19. Spectroscopy: Probing Molecules with Light
19. Spectroscopy: Probing Molecules with Light
20
20. Hydrogen Atom I
20. Hydrogen Atom I
21
21. Hydrogen Atom II; Rydberg States
21. Hydrogen Atom II; Rydberg States
22
22. Helium Atom
22. Helium Atom
23
23. Many-Electron Atoms
23. Many-Electron Atoms
24
24. Molecular Orbital Theory I; Variational Principle and Matrix Mechanics
24. Molecular Orbital Theory I; Variational Principle and Matrix Mechanics
25
25. Molecular Orbital Theory II; H2+, A2, AB Diatomics
25. Molecular Orbital Theory II; H2+, A2, AB Diatomics
26
26. Qualitative MO Theory: Hückel
26. Qualitative MO Theory: Hückel
27
27. Non-Degenerate Perturbation Theory III
27. Non-Degenerate Perturbation Theory III
28
28. Modern Electronic Structure Theory: Basis Sets
28. Modern Electronic Structure Theory: Basis Sets
29
29. Modern Electronic Structure Theory: Electronic Correlation
29. Modern Electronic Structure Theory: Electronic Correlation
30
30. Time-Dependent Perturbation Theory I: H is Time-Independent, Zewail Wavepacket.
30. Time-Dependent Perturbation Theory I: H is Time-Independent, Zewail Wavepacket.
31
31. Time-Dependent Perturbation Theory II: H is Time-Dependent: Two-Level Problem
31. Time-Dependent Perturbation Theory II: H is Time-Dependent: Two-Level Problem
32
32. Intermolecular Interactions by Non-Degenerate Perturbation Theory
32. Intermolecular Interactions by Non-Degenerate Perturbation Theory
33
33. Electronic Spectroscopy: Franck-Condon
33. Electronic Spectroscopy: Franck-Condon
34
34. Electronic Spectroscopy and Photochemistry
34. Electronic Spectroscopy and Photochemistry
35
35. Delta-Functions, Eigen-Functions of X, Discrete Variable Representation
35. Delta-Functions, Eigen-Functions of X, Discrete Variable Representation
36
36. Time Dependence of Two-Level Systems: Density Matrix, Rotating Wave Approximation
36. Time Dependence of Two-Level Systems: Density Matrix, Rotating Wave Approximation