1 1. The Importance of Chemical Principles 1 1. The importance of chemical principles 1 Lec 1 | MIT 5.111 Principles of Chemical Science, Fall 2005 2 2. Atomic Structure 2 2. Discovery of electron and nucleus, need for quantum mechanics 2 Lec 2 | MIT 5.111 Principles of Chemical Science, Fall 2005 3 3. Wave-Particle Duality of Light 3 3. Wave-particle duality of light 3 Lec 3 | MIT 5.111 Principles of Chemical Science, Fall 2005 4 4. Wave-Particle Duality of Matter; Schrödinger Equation 4 4. Wave-particle duality of matter, Schrödinger equation 4 Lec 4 | MIT 5.111 Principles of Chemical Science, Fall 2005 5 5. Hydrogen Atom Energy Levels 5 5. Hydrogen atom energy levels 5 Lec 5 | MIT 5.111 Principles of Chemical Science, Fall 2005 6 6. Hydrogen Atom Wavefunctions (Orbitals) 6 6. Hydrogen atom wavefunctions (orbitals) 6 Lec 6 | MIT 5.111 Principles of Chemical Science, Fall 2005 7 7. Multielectron Atoms 7 7. p-orbitals 7 Lec 7 | MIT 5.111 Principles of Chemical Science, Fall 2005 8 8. The Periodic Table and Periodic Trends 8 8. Multielectron atoms and electron configurations 8 Lec 8 | MIT 5.111 Principles of Chemical Science, Fall 2005 9 9. Periodic Table; Ionic and Covalent Bonds 9 9. Periodic trends 9 Lec 9 | MIT 5.111 Principles of Chemical Science, Fall 2005 10 10. Lewis Structures 10 10. Periodic trends continued; Covalent bonds 10 Lec 10 | MIT 5.111 Principles of Chemical Science, Fall 2005 11 11. Formal Charge and Resonance 11 11. Lewis structures 11 Lec 11 | MIT 5.111 Principles of Chemical Science, Fall 2005 12 12. The Shapes of Molecules: VSEPR Theory 12 12. Exceptions to Lewis structure rules; Ionic bonds 12 Lec 12 | MIT 5.111 Principles of Chemical Science, Fall 2005 13 13. Molecular Orbital Theory 13 13. Polar covalent bonds; VSEPR theory 13 Lec 13 | MIT 5.111 Principles of Chemical Science, Fall 2005 14 14. Valence Bond Theory and Hybridization 14 14. Molecular orbital theory 14 Lec 14 | MIT 5.111 Principles of Chemical Science, Fall 2005 15 15. Thermodynamics: Bond and Reaction Enthalpies 15 15. Valence bond theory and hybridization 15 Lec 15 | MIT 5.111 Principles of Chemical Science, Fall 2005 16 16. Thermodynamics: Gibbs Free Energy and Entropy 16 16. Determining hybridization in complex molecules; Thermochemistry, bond energies/bond enthalpies 16 Lec 16 | MIT 5.111 Principles of Chemical Science, Fall 2005 17 17. Thermodynamics: Now What Happens When You Heat It Up? 17 17. Entropy and disorder 17 Lec 17 | MIT 5.111 Principles of Chemical Science, Fall 2005 18 18. Introduction to Chemical Equilibrium 18 18. Free energy and control of spontaneity 18 Lec 18 | MIT 5.111 Principles of Chemical Science, Fall 2005 19 19. Chemical Equilibrium: Le Châtelier’s Principle 19 19. Chemical equilibrium 19 Lec 19 | MIT 5.111 Principles of Chemical Science, Fall 2005 20 20. Solubility and Acid-Base Equilibrium 20 20. Le Chatelier's principle and applications to blood-oxygen levels 20 Lec 20 | MIT 5.111 Principles of Chemical Science, Fall 2005 21 21. Acid-Base Equilibrium: Is MIT Water Safe to Drink? 21 21. Acid-base equilibrium: Is MIT water safe to drink? 21 Lec 21 | MIT 5.111 Principles of Chemical Science, Fall 2005 22 22. Acid-Base Equilibrium: Salt Solutions and Buffers 22 22. Chemical and biological buffers 22 Lec 22 | MIT 5.111 Principles of Chemical Science, Fall 2005 23 23. Acid-Base Titrations Part I 23 23. Acid-base titrations 23 Lec 23 | MIT 5.111 Principles of Chemical Science, Fall 2005 24 24. Acid-Base Titrations Part II 24 24. Balancing oxidation/reduction equations 24 Lec 24 | MIT 5.111 Principles of Chemical Science, Fall 2005 25 25. Oxidation-Reduction and Electrochemical Cells 25 25. Electrochemical cells 25 Lec 25 | MIT 5.111 Principles of Chemical Science, Fall 2005 26 26. Chemical and Biological Oxidations 26 26. Chemical and biological oxidation/reduction reactions 26 Lec 26 | MIT 5.111 Principles of Chemical Science, Fall 2005 27 27. Introduction to Transition Metals 27 27. Transition metals and the treatment of lead poisoning 27 Lec 27 | MIT 5.111 Principles of Chemical Science, Fall 2005 28 28. Transition Metals: Crystal Field Theory Part I 28 28. Crystal field theory 28 Lec 28 | MIT 5.111 Principles of Chemical Science, Fall 2005 29 29. Transition Metals: Crystal Field Theory Part II 29 29. Metals in biology 29 Lec 29 | MIT 5.111 Principles of Chemical Science, Fall 2005 30 30. Kinetics: Rate Laws 30 30. Magnetism and spectrochemical theory 30 Lec 30 | MIT 5.111 Principles of Chemical Science, Fall 2005 31 31. Nuclear Chemistry and Chemical Kinetics 31 31. Rate laws 31 Lec 31 | MIT 5.111 Principles of Chemical Science, Fall 2005 32 32. Kinetics: Reaction Mechanisms 32 32. Nuclear chemistry and elementary reactions 32 Lec 32 | MIT 5.111 Principles of Chemical Science, Fall 2005 33 33. Kinetics and Temperature 33 33. Reaction mechanism 33 Lec 33 | MIT 5.111 Principles of Chemical Science, Fall 2005 34 34. Kinetics: Catalysts 34 34. Temperature and kinetics 34 Lec 34 | MIT 5.111 Principles of Chemical Science, Fall 2005 35 35. Applying Chemical Principles 35 35. Enzyme catalysis 35 Lec 35 | MIT 5.111 Principles of Chemical Science, Fall 2005 36 36. Biochemistry 36 Lec 36 | MIT 5.111 Principles of Chemical Science, Fall 2005