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Uedu Open / Principles of Chemical Science
5.111

Principles of Chemical Science

Prof. Catherine Drennan, Dr. Elizabeth Vogel Taylor | Fall 2008
Science & Math Chemistry Science
前往原始課程
CC BY-NC-SA 4.0
課程簡介

This course provides an introduction to the chemistry of biological, inorganic, and organic molecules. The emphasis is on basic principles of atomic and molecular electronic structure, thermodynamics, acid-base and redox equilibria, chemical kinetics, and catalysis.

In an effort to illuminate connections between chemistry and biology, a list of the biology-, medicine-, and MIT research-related examples used in 5.111 is provided in Biology-Related Examples.

Acknowledgements

Development and implementation of the biology-related materials in this course were funded through an HHMI Professors grant to Prof. Catherine L. Drennan. Videos and captioning were made possible and supported by the MIT Class of 2009.

課程資訊
來源MIT 開放式課程
科系Chemistry
語言English
影片數107
課程影片 (107)
1
1. The Importance of Chemical Principles
1. The Importance of Chemical Principles
1
1. The importance of chemical principles
1. The importance of chemical principles
1
Lec 1 | MIT 5.111 Principles of Chemical Science, Fall 2005
Lec 1 | MIT 5.111 Principles of Chemical Science, Fall 2005
2
2. Atomic Structure
2. Atomic Structure
2
2. Discovery of electron and nucleus, need for quantum mechanics
2. Discovery of electron and nucleus, need for quantum mechanics
2
Lec 2 | MIT 5.111 Principles of Chemical Science, Fall 2005
Lec 2 | MIT 5.111 Principles of Chemical Science, Fall 2005
3
3. Wave-Particle Duality of Light
3. Wave-Particle Duality of Light
3
3. Wave-particle duality of light
3. Wave-particle duality of light
3
Lec 3 | MIT 5.111 Principles of Chemical Science, Fall 2005
Lec 3 | MIT 5.111 Principles of Chemical Science, Fall 2005
4
4. Wave-Particle Duality of Matter; Schrödinger Equation
4. Wave-Particle Duality of Matter; Schrödinger Equation
4
4. Wave-particle duality of matter, Schrödinger equation
4. Wave-particle duality of matter, Schrödinger equation
4
Lec 4 | MIT 5.111 Principles of Chemical Science, Fall 2005
Lec 4 | MIT 5.111 Principles of Chemical Science, Fall 2005
5
5. Hydrogen Atom Energy Levels
5. Hydrogen Atom Energy Levels
5
5. Hydrogen atom energy levels
5. Hydrogen atom energy levels
5
Lec 5 | MIT 5.111 Principles of Chemical Science, Fall 2005
Lec 5 | MIT 5.111 Principles of Chemical Science, Fall 2005
6
6. Hydrogen Atom Wavefunctions (Orbitals)
6. Hydrogen Atom Wavefunctions (Orbitals)
6
6. Hydrogen atom wavefunctions (orbitals)
6. Hydrogen atom wavefunctions (orbitals)
6
Lec 6 | MIT 5.111 Principles of Chemical Science, Fall 2005
Lec 6 | MIT 5.111 Principles of Chemical Science, Fall 2005
7
7. Multielectron Atoms
7. Multielectron Atoms
7
7. p-orbitals
7. p-orbitals
7
Lec 7 | MIT 5.111 Principles of Chemical Science, Fall 2005
Lec 7 | MIT 5.111 Principles of Chemical Science, Fall 2005
8
8. The Periodic Table and Periodic Trends
8. The Periodic Table and Periodic Trends
8
8. Multielectron atoms and electron configurations
8. Multielectron atoms and electron configurations
8
Lec 8 | MIT 5.111 Principles of Chemical Science, Fall 2005
Lec 8 | MIT 5.111 Principles of Chemical Science, Fall 2005
9
9. Periodic Table; Ionic and Covalent Bonds
9. Periodic Table; Ionic and Covalent Bonds
9
9. Periodic trends
9. Periodic trends
9
Lec 9 | MIT 5.111 Principles of Chemical Science, Fall 2005
Lec 9 | MIT 5.111 Principles of Chemical Science, Fall 2005
10
10. Lewis Structures
10. Lewis Structures
10
10. Periodic trends continued; Covalent bonds
10. Periodic trends continued; Covalent bonds
10
Lec 10 | MIT 5.111 Principles of Chemical Science, Fall 2005
Lec 10 | MIT 5.111 Principles of Chemical Science, Fall 2005
11
11. Formal Charge and Resonance
11. Formal Charge and Resonance
11
11. Lewis structures
11. Lewis structures
11
Lec 11 | MIT 5.111 Principles of Chemical Science, Fall 2005
Lec 11 | MIT 5.111 Principles of Chemical Science, Fall 2005
12
12. The Shapes of Molecules: VSEPR Theory
12. The Shapes of Molecules: VSEPR Theory
12
12. Exceptions to Lewis structure rules; Ionic bonds
12. Exceptions to Lewis structure rules; Ionic bonds
12
Lec 12 | MIT 5.111 Principles of Chemical Science, Fall 2005
Lec 12 | MIT 5.111 Principles of Chemical Science, Fall 2005
13
13. Molecular Orbital Theory
13. Molecular Orbital Theory
13
13. Polar covalent bonds; VSEPR theory
13. Polar covalent bonds; VSEPR theory
13
Lec 13 | MIT 5.111 Principles of Chemical Science, Fall 2005
Lec 13 | MIT 5.111 Principles of Chemical Science, Fall 2005
14
14. Valence Bond Theory and Hybridization
14. Valence Bond Theory and Hybridization
14
14. Molecular orbital theory
14. Molecular orbital theory
14
Lec 14 | MIT 5.111 Principles of Chemical Science, Fall 2005
Lec 14 | MIT 5.111 Principles of Chemical Science, Fall 2005
15
15. Thermodynamics: Bond and Reaction Enthalpies
15. Thermodynamics: Bond and Reaction Enthalpies
15
15. Valence bond theory and hybridization
15. Valence bond theory and hybridization
15
Lec 15 | MIT 5.111 Principles of Chemical Science, Fall 2005
Lec 15 | MIT 5.111 Principles of Chemical Science, Fall 2005
16
16. Thermodynamics: Gibbs Free Energy and Entropy
16. Thermodynamics: Gibbs Free Energy and Entropy
16
16. Determining hybridization in complex molecules; Thermochemistry, bond energies/bond enthalpies
16. Determining hybridization in complex molecules; Thermochemistry, bond energies/bond enthalpies
16
Lec 16 | MIT 5.111 Principles of Chemical Science, Fall 2005
Lec 16 | MIT 5.111 Principles of Chemical Science, Fall 2005
17
17. Thermodynamics: Now What Happens When You Heat It Up?
17. Thermodynamics: Now What Happens When You Heat It Up?
17
17. Entropy and disorder
17. Entropy and disorder
17
Lec 17 | MIT 5.111 Principles of Chemical Science, Fall 2005
Lec 17 | MIT 5.111 Principles of Chemical Science, Fall 2005
18
18. Introduction to Chemical Equilibrium
18. Introduction to Chemical Equilibrium
18
18. Free energy and control of spontaneity
18. Free energy and control of spontaneity
18
Lec 18 | MIT 5.111 Principles of Chemical Science, Fall 2005
Lec 18 | MIT 5.111 Principles of Chemical Science, Fall 2005
19
19. Chemical Equilibrium: Le Châtelier’s Principle
19. Chemical Equilibrium: Le Châtelier’s Principle
19
19. Chemical equilibrium
19. Chemical equilibrium
19
Lec 19 | MIT 5.111 Principles of Chemical Science, Fall 2005
Lec 19 | MIT 5.111 Principles of Chemical Science, Fall 2005
20
20. Solubility and Acid-Base Equilibrium
20. Solubility and Acid-Base Equilibrium
20
20. Le Chatelier's principle and applications to blood-oxygen levels
20. Le Chatelier's principle and applications to blood-oxygen levels
20
Lec 20 | MIT 5.111 Principles of Chemical Science, Fall 2005
Lec 20 | MIT 5.111 Principles of Chemical Science, Fall 2005
21
21. Acid-Base Equilibrium: Is MIT Water Safe to Drink?
21. Acid-Base Equilibrium: Is MIT Water Safe to Drink?
21
21. Acid-base equilibrium: Is MIT water safe to drink?
21. Acid-base equilibrium: Is MIT water safe to drink?
21
Lec 21 | MIT 5.111 Principles of Chemical Science, Fall 2005
Lec 21 | MIT 5.111 Principles of Chemical Science, Fall 2005
22
22. Acid-Base Equilibrium: Salt Solutions and Buffers
22. Acid-Base Equilibrium: Salt Solutions and Buffers
22
22. Chemical and biological buffers
22. Chemical and biological buffers
22
Lec 22 | MIT 5.111 Principles of Chemical Science, Fall 2005
Lec 22 | MIT 5.111 Principles of Chemical Science, Fall 2005
23
23. Acid-Base Titrations Part I
23. Acid-Base Titrations Part I
23
23. Acid-base titrations
23. Acid-base titrations
23
Lec 23 | MIT 5.111 Principles of Chemical Science, Fall 2005
Lec 23 | MIT 5.111 Principles of Chemical Science, Fall 2005
24
24. Acid-Base Titrations Part II
24. Acid-Base Titrations Part II
24
24. Balancing oxidation/reduction equations
24. Balancing oxidation/reduction equations
24
Lec 24 | MIT 5.111 Principles of Chemical Science, Fall 2005
Lec 24 | MIT 5.111 Principles of Chemical Science, Fall 2005
25
25. Oxidation-Reduction and Electrochemical Cells
25. Oxidation-Reduction and Electrochemical Cells
25
25. Electrochemical cells
25. Electrochemical cells
25
Lec 25 | MIT 5.111 Principles of Chemical Science, Fall 2005
Lec 25 | MIT 5.111 Principles of Chemical Science, Fall 2005
26
26. Chemical and Biological Oxidations
26. Chemical and Biological Oxidations
26
26. Chemical and biological oxidation/reduction reactions
26. Chemical and biological oxidation/reduction reactions
26
Lec 26 | MIT 5.111 Principles of Chemical Science, Fall 2005
Lec 26 | MIT 5.111 Principles of Chemical Science, Fall 2005
27
27. Introduction to Transition Metals
27. Introduction to Transition Metals
27
27. Transition metals and the treatment of lead poisoning
27. Transition metals and the treatment of lead poisoning
27
Lec 27 | MIT 5.111 Principles of Chemical Science, Fall 2005
Lec 27 | MIT 5.111 Principles of Chemical Science, Fall 2005
28
28. Transition Metals: Crystal Field Theory Part I
28. Transition Metals: Crystal Field Theory Part I
28
28. Crystal field theory
28. Crystal field theory
28
Lec 28 | MIT 5.111 Principles of Chemical Science, Fall 2005
Lec 28 | MIT 5.111 Principles of Chemical Science, Fall 2005
29
29. Transition Metals: Crystal Field Theory Part II
29. Transition Metals: Crystal Field Theory Part II
29
29. Metals in biology
29. Metals in biology
29
Lec 29 | MIT 5.111 Principles of Chemical Science, Fall 2005
Lec 29 | MIT 5.111 Principles of Chemical Science, Fall 2005
30
30. Kinetics: Rate Laws
30. Kinetics: Rate Laws
30
30. Magnetism and spectrochemical theory
30. Magnetism and spectrochemical theory
30
Lec 30 | MIT 5.111 Principles of Chemical Science, Fall 2005
Lec 30 | MIT 5.111 Principles of Chemical Science, Fall 2005
31
31. Nuclear Chemistry and Chemical Kinetics
31. Nuclear Chemistry and Chemical Kinetics
31
31. Rate laws
31. Rate laws
31
Lec 31 | MIT 5.111 Principles of Chemical Science, Fall 2005
Lec 31 | MIT 5.111 Principles of Chemical Science, Fall 2005
32
32. Kinetics: Reaction Mechanisms
32. Kinetics: Reaction Mechanisms
32
32. Nuclear chemistry and elementary reactions
32. Nuclear chemistry and elementary reactions
32
Lec 32 | MIT 5.111 Principles of Chemical Science, Fall 2005
Lec 32 | MIT 5.111 Principles of Chemical Science, Fall 2005
33
33. Kinetics and Temperature
33. Kinetics and Temperature
33
33. Reaction mechanism
33. Reaction mechanism
33
Lec 33 | MIT 5.111 Principles of Chemical Science, Fall 2005
Lec 33 | MIT 5.111 Principles of Chemical Science, Fall 2005
34
34. Kinetics: Catalysts
34. Kinetics: Catalysts
34
34. Temperature and kinetics
34. Temperature and kinetics
34
Lec 34 | MIT 5.111 Principles of Chemical Science, Fall 2005
Lec 34 | MIT 5.111 Principles of Chemical Science, Fall 2005
35
35. Applying Chemical Principles
35. Applying Chemical Principles
35
35. Enzyme catalysis
35. Enzyme catalysis
35
Lec 35 | MIT 5.111 Principles of Chemical Science, Fall 2005
Lec 35 | MIT 5.111 Principles of Chemical Science, Fall 2005
36
36. Biochemistry
36. Biochemistry
36
Lec 36 | MIT 5.111 Principles of Chemical Science, Fall 2005
Lec 36 | MIT 5.111 Principles of Chemical Science, Fall 2005